Wednesday, October 30, 2019

A Critical Assessment of an Agency or Funding Regime that promotes Essay - 1

A Critical Assessment of an Agency or Funding Regime that promotes physical regeneration - Essay Example ese agencies and their functioning toward the uplift of the regional economy, it would be interesting to study and understand what urban regeneration is all about and how it evolved. Urban areas are essentially dynamic in nature. Socio-economic factors, environmental and physical factors all interplay and interact together to generate changes in their structures. Moreover, an urban area experiences thrusts from outside which necessitates adaptation to changes while internal dynamics and pressure try to withstand such changes or accept those resulting in either prosperity or decline. Though each problem may not be unique to a specific rural area, yet each challenge requires a distinctive approach towards the generation and implementation of its solution. Since the beginning, urban areas have always performed a variety of functions, offering shelter, providing infrastructure and opportunities for trade and commerce and opportunities for social interaction, being a few of those. As time passed, the importance of each need changed necessitating the requirement for new infrastructure, more space, more facilities for business etc. These changes in the physical structure and functioning of a town and its social life are inevitable since the town has to reorganise itself to meet the changing demands. These changes are also beneficial in a somewhat indirect way since these changes also make fresh demands for improvement of infrastructure and facilities so that the community within an urban area is forced to adjust itself to the new demands and work towards providing better opportunities for growth and progress. The relation between social deprivation and meagre physical infrastructure and facilities had long been an accepted fact and legislations and policies were implemented for improved infrastructure for health and better living conditions. It was gradually realised that merely improving health and living conditions will not contribute significantly towards the

Sunday, October 27, 2019

Structure of Water and Its Dynamic Hydrogen Bond Network

Structure of Water and Its Dynamic Hydrogen Bond Network Introduction Water is essential to life as it is main constituent of cell in living organism. All biological macromolecules are almost inactive in its structural stability and functioning in absence of water. Water-Role in Life Water is key compound for our existence on this planet due to its ubiquitous presence on the earth and in living organisms. It is involved in all chemical, biological and geological processes. Due to its anomalous behavior it named as ‘matrix of life’, ‘solvent of life’. It plays a vital role from molecule and cell to tissues and organisms.1-4 In past several decades water has attracted the most scientific attention among the liquid due to its anomalous properties. It shows peculiar properties such as negative volume of melting, density maximum at 277 K, high melting and boiling point, high dielectric constant, minimum in the isobaric heat capacity and isothermal compressibility at 308 K and 319 K, respectively, high mobility transport for H+ and OH ions. The density of most liquids increases as it freeze but in case of water it expands about 11% due to which ice floats on water. It is the solvent of life and plays an important role in protein interactions a nd stabilization of protein structure. The work of Kauzmann gives the importance of water in protein folding and its interactions with water.5 Structure of Liquid Water The anomalous behavior of water is due to its unique ability to form a network of self associated molecules through hydrogen bonding. To study the structure of water and its dynamic hydrogen bond network large number of studies has been carried out.1-12 Still many aspects of water are not fully understand at molecular level. Dyke and co-workers first reported existence of H-bonding in vapor phase experimentally and measured the H-bond length as 2.98 Ã… in water dimer using molecular beam resonance technique which is higher than water in solid (for ice H-bond strength 2.74 Ã…) and liquid (2.85 Ã…) indicates the H-bond strength is weaker in Gas phase.13 From X-ray diffraction study of Bernal and Fowler and Morgan and Warren it is revealed that water is tetrahedrally coordinated through hydrogen bonds similar to the structure of ice I (Figure 1.1). 14-15The number of theories for the water structure has been proposed based on different techniques such as X-ray, neutron diffraction, dielectric relaxation and Raman spectroscopy. 16-22. These theories are generally classified into two models as a) Continuum model and b) Mixture model. Figure 1.1 Crystal structure of ice I at low pressure Continuum model In continuum model it is assumed that almost completely hydrogen bonded water molecules in a continuous network. Pople described the continuum model which is agreement with the observed variation of X-ray radial distribution function with temperature. 23According to Pople In continuous bonded network of the water bond bending and deformations occurs instead of bond water. Recently, Rice and Sceats 24proposed Random Network Model (RNM), which explains the continuum model and it is further developed by Henn and Kauzmann. 25This model is used for determining the heat capacity contribution due to water-water interactions. b) Mixture model In mixture model water consists of differently H-bonded species with zero, one or both hydrogens are engaged in hydrogen bonding. Franks and Wen 26 gives the â€Å"Flickering Cluster† model in which cooperative H-bonding is observed in water molecules. The co-operativity involves the hydrogen bond formation of one bonding site of water molecule contributes the delocalization energy to the molecule, which is involved in hydrogen bonding with another water molecule. According to Franks and Wen the clusters of the water molecules (bulk water) and free monomer molecules (dense water) are in equilibrium with each other. Samoilov 27 proposed the interstitial model in which water molecules are present in the cavities of ice lattice. Nemethy and Scheraga 28 used statistical thermodynamic model to calculate the Helmholtz free energy, internal energy and entropy as a function of temperature. Also the water hydrate model proposed by Pauling. 29 Now a days, theoretical techniques such as Monto Carlo, molecular dynamic simulation are used to study structural behavior of water. It provides most promising approach for the study of water at molecular level. Jorgensen 30 has developed transferable intermolecular potential functions (TIPS) suitable for use in liquid simulations for water. This potential has been used by Jorgensen and Madura 31 in MC simulation on liquid water to study the effect of temperature on vaporization, hydrogen bonding, density, isothermal compressibility and radial distribution functions. Number of water models such as SPC, TIP3P, TIP4P, TIP5P are developed for the molecular simulation of large biomolecular systems. Figure 1.2 Frank-Wen Flickering Cluster Model of Liquid Water 1.2 Hydrophobic Hydration and Hydrophobic Interactions The weak non-covalent interactions like van der Waals forces, H-bonding, ion-dipole, hydrophobic interactions are responsible for change in the structure of water around the solute molecule. The hydrophobic interaction is the prominent factor in the solvation of apolar or non-polar molecule. When a non-polar solute is dissolve in water there is large negative change in entropy. The disruption in the normal H-bonded structure is occurred and new H-bonded cage-like structure is formed around the solute molecule. So the structure formed is more ordered than the ordinary water. The term hydrophobic hydration is used when non-polar solute solvated by the cage of the solvent molecule around it. The short lived aggregates are formed around the solute molecule. The formation of polymeric aggregates strengthens the hydrogen bonding which gives negative contribution to ΔH0. 10 The hydrophobic interactions are important in a field of biochemistry for the purpose of conformational stability of biological macromolecules, protein folding, aggregation, ion transport, drug delivery as well as in industry. Usually hydrophobic hydration occurs in non-polar compounds such as alcohols, ethers, and amines. The tetraalkylammonium (TAA) salts with larger cation also shows the hydrophobic hydration effect. Kustov gives the effect of size of cation on the hydrophobic hydration. He studied the specific heat of solution for the higher size cation TAA salts and observed that as the size of cation in salt increases the specific heat of solution and hydration increases upto the tetrapentylammonium salts and then decreases. As the specific heat of solution increases the hydrophobic hydration increases. For the hexyl and heptyltetraalkylammonium salts the ΔC0p decreases so the hydrophobic hydration weakens. Thus hydrophobic hydration depends on the size of cation of TAA. Th e hydrophobic interaction is best explained by Goring et al. by studying the interaction of non-electrolytes in aqueous solutions by dilatometrically. They compared the apparent specific volume (à Ã¢â‚¬ ¢2) relative to apparent specific volume at 0  ºC as function of temperature for non-electrolytes and showed that 1-butanol behaves like hydrophobic compound and acts as structure maker in aqueous solution while glycerol with polar groups disrupts the structure of water. The hydrophobic compound shows the slope dà Ã¢â‚¬ ¢2/dT is less than the corresponding thermal expansions of pure compound while it greater for the hydrophilic compounds. Madan and Sharp explained that non-polar solutes have large capacity heat of hydration ΔCp while for polar solutes it is small negative. The large change in heat capacity at high temperature is due to unfavorable enthalpic interacions and not due to entropy change. The effect of salt on the hydrophobic hydration was carried out by Talukdar and Kundu and observed that hydrophobic cation induce more hydrophobic hydration in aqueous NaNO3 solution than in pure water. Rossky et al. with the help of computer simulation studied the hydration properties of the interfaces between the water and the hydrophobic surfaces for the active peptide melittin in its monomeric and dimeric form and concluded that hydrophobic hydration is depends on the surface topography of biomolecule. 1.3 Spectroscopic study of water Due to its various anomalous properties and great importance in the several field water is the most studied compound. To study the structure of water, number of spectroscopic techniques such as IR, Raman, neutron diffraction, X-ray scattering, NMR spectroscopy etc. have been used still today. The spectroscopy and scattering studies provides the structural information of water at molecular level. Bernal and Fowler analyzed the X-ray diffraction of water and investigated water as distorted quartz-like. The hydrogen bond network in water is found to be tetrahedral in nature and each water molecule can be bound with another four water molecules i.e. each water molecule is double proton donor and double proton acceptor. While recently, Wernet et al. studied the structure of water by soft X-ray absorption spectroscopy and X-ray Raman scattering and investigate that hydrogen bond network in the water consists of only two strong hydrogen bonds and one act as proton door and another as proton acceptor. This controversial result of structure of water from earlier study makes the scientist to study the water structure more interesting. In this context, number of scientists have been studied the water structure by X-ray absorption spectroscopy. Infrared and Raman techniques are also the important sources of the information of hydrogen bonding in water. Above the absolute temperature all the atoms in the molecules are in continuously vibrating motion with respect to each other. Any molecule absorbs the radiation when frequency of a specific vibration is equal to frequency of the IR radiation directed on the molecule. Each atom has three degrees of freedom, corresponding to motions of the three Cartesian coordinate axes (x, y, z). Total no of coordinate values is 3N for a molecule containing N atoms. Thus, Water has 9 degrees of freedom with C2v symmetry. It shows the two stretching vibrations (symmetric and asymmetric), one bending vibration, three hindered rotations (librations), and three hindered translations. Earlier, number of research papers has been published on the study of the structure of water in solid, liquid as well as in vapor phase by IR and Raman technique. The fundamental IR frequencies for the H2O and heavy water is as shown in Table Table: Fundamental vibrations of liquid ordinary water and heavy water Vibration(s) liquid H2O (25  °C) liquid D2O (25  °C) liquid T2O v, cm-1 ÃŽ µÃŽ », M-1cm-1 v, cm-1 ÃŽ µÃŽ », M-1cm-1 v, cm-1 v2 1643.5 21.65 1209.4 17.10 1024 combination ofv2+ libration 2127.5 3.46 1555.0 1.88 v1,v3, and overtone ofv2 3404.0 100.61 2504.0 69.68 2200 http://www1.lsbu.ac.uk/water/water_vibrational_spectrum.html Walrafen investigated the structure of water by Raman spectroscopy in the intermolecular as well as intramolecular vibrational region. From Raman scattering it is observed that for liquid H2O and D2O a broad weak hydrogen bending band at 60 cm-1 and it is observed to be decreases as temperature rise, the band near 170 cm-1 is produced by the stretching motion of O-H band in water molecule. This is also decreases as increases in temperature which indicates the structural breakdown of water units. These vibrations are the intermolecular vibrations of water which are observed in the restricted translational region. The intramolecular vibrations of water occurs in the range of 2000-4000 cm-1.Walrafen studied the Raman spectra of 50 mole % solution of H2O and D2O in the intramolecular region in which principle contribution of HDO vibrations are studied. The two maxima at 3415 ±5 cm-1 and 2495 ±5 cm-1 are referred due to OH and OD stretching vibrations of HDO, and of H2O and D2O. Also the weak band at 2860 ± 10 cm-1 arises from the overtone of the fundamental intramolecular bending vibration of HDO near 1450 cm-1. When H2O, D2O mixture studied at 32.2 to 93  ºC, the isosbestic point observed at 2570 ±5 cm-1 indicates the equilibrium exists between hydrogen bonded and nonhydrogen bonded OD stretching vibrations. Senior and Verrall observed same results when studied the HDO stretching at temperature 29 to 87  ºC by infrared spectroscopy. Bakker et al. studied the lifetime of the OH-stretching vibration in the water as a function of temperature by using femtosecond mid-infrared pump-probe spectroscopy and observed that it increases from 260 ±18 (at 298 K) to 320 ±18 (at 358 K) Recently, molecular dynamic simulation is becomes the fast method for the structural detection at molecular level. Xantheas et al. used the ab initio method to obtain the vibrational frequencies as well as zero point energy for the water clusters and its isomers with the help of second-order Mà ¸ller–Plesset perturbation level of theory (MP2) with the augmented correlation consistent basis set of double zeta quality (aug-cc-pVDZ). 1.3.1 Near-Infrared spectral study of water and aqueous solutions Near-Infrared consists of the region 800-2500 nm (12500-4000 cm‑1) in the electromagnetic spectrum. In this region molecule have energy sufficient to excite first (2ÃŽ ½), second (3ÃŽ ½), and higher overtones (nÃŽ ½) vibrations. The overtones observed in the molecule when the intermolecular vibrations of the molecules do not obey the Hook’s law. The band is more intense when the greater the anharmonicity. The combination bands are also observed in the same region. Near infrared spectroscopy is the basic tool to study the hydrogen bonding in molecule. Earlier, the scientist Luck studied water and alcohol in the NIR region and observed that the strength of cooperativity of H-bond in water is about 250 % stronger than H-bond in a monomeric water. Different species of water present in the cooperative H-bond such as H-non bonded, H-bond strong and H-bond weaker. Ozaki et al. studied the structure of water by using two analytical techniques such as two dimensional correlation spectroscopy and principal component analysis in which they showed the two-state water model by measurements of the water at different temperatures from 6 to 80  ºC. Two bands are observed at 1412 and 1491 nm due to two different species of water i.e. weak H-bond and strong H-bond respectively. The species observed at 1438 nm which has no much effect of temperature which suggested may be due to distorted two-state model of water. The water at high temperature and pressure rem arkably exhibits different properties than at ambient temperature. It becomes good solvent for hydrophobic substance such as benzene and hydrocarbons which are non-polar gets completely miscible at certain temperature and pressure. The effect of high temperature as well as pressure has been given by Ikawa et al. in the range of 5500 to 7800 cm-1. They observed the band at 7000 cm-1 gradually shifts to higher wavenumber is due to free OH vibrations and at 673 K and 400 bar pressure the absorption band retain the rotational features i.e. water molecule quite rotate freely though there is collision with other molecules. Recently, Near-Infrared spectroscopy has been used extensively for chemical analysis and characterization. The applications of NIR spectroscopy in various fields have attracted the scientific community. It is also used in the determination of moisture content in food samples. It can be used to probe the hydration effects in aqueous solutions of salt. Wu et al. have studied the effect of ethanol on the structural organization of aqueous solutions of [Bmim][BF4] and [Amim][Cl] using one-dimensional and 2D correlation NIR spectroscopy. They showed that hydrogen bonding between water and ILs gets reduced in presence of high concentration of ethanol32 and can be used to remove water as an impurity in hygroscopic ILs. They also used this technique to study aggregation behavior of ILs in water. NIR spectroscopy has been used previously for the study of hydration by McCabe and Fisher in which they have studied the hydration of perchlorate and alkali halides in aqueous solutions by using excl uded volume. Koga et al. have given the excess molar absorptivity in the range of 4600-5500 cm-1 i.e. (ÃŽ ½2+ÃŽ ½3) combination band of water for the Na halides and concluded that the Br‑ and I form the hydrogen bond directly with the water network which is different than the Cl ion. Bonner and Woolsey have obtained the hydration number for some alkali halides by using the 958 nm (2ÃŽ ½1+ÃŽ ½3) combination band of water. By applying their method, Hollenberg et al. calculated the hydration number for amino acids and carbohydrates The new concept introduced by Noda in 1993 i.e. two dimensional correlation spectroscopy has attracted many scientist to study effect of solutes on the structure of water by IR as well as NIR spectroscopy. This technique becomes powerful tool for the elucidation of spectral changes induced by temperature, time and concentration. Noda et al. studied the structural and crystallization dynamics of poly(L-lactide) during isothermal cold crystallization by two dimensional correlation spectroscopy. An interpretation of the evolution with temperature of the ÃŽ ½2+ÃŽ ½3 combination band in water V. Fornà ©s and J. Chaussidon, J. Chem. Phys. 68, 4667-4671 (1978) Near-infrared spectroscopic study of water at high temperatures and pressures Yusuke Jin and Shun-ichi Ikawa J. Chem. Phys., 119(23), 12432-12438, 2003. The importance of cooperativity for the properties of liquid water W.A.P. Luck Journal of Molecular Structure, 448 (1998) 131 142. Studies on the Structure of Water Using Two-Dimensional Near-Infrared Correlation Spectroscopy and Principal Component Analysis V. H. Segtnan, S. Sasic, T. Isaksson, Y. Ozaki Anal. Chem. 2001, 73, 3153-3161

Friday, October 25, 2019

Media Violence Against Women Essay -- Argumentative Persuasive Topics

Media Violence Against Women      Ã‚  Ã‚   In the United States, as well as throughout the majority of the world, people are bombarded with information on a daily basis.   The majority of the information that it seen or heard is a direct result of someone   aiming the information at the masses.   Whether it is a company that would like us to buy it's product, or a newspaper that would have us believe a certain "fact" that they are reporting, someone has decided how the information will be presented.   This notion brings me to the issue of how our society perpetuates violence against women through the use of the media and television shows.   I would argue that, because we are socialized on a daily basis to believe certain ideas, this same process contributes to the violence aimed toward women.   This encompasses the concept that impressionable young men may remain unaware of the impact of this violence by the omission of certain facts from news articles.   It is also important to   see how the medi a contributes to the way in which the abused women see their role in the "creation" of this violence.   Furthermore, I would reason that these media outlets create a certain type of apathy in our society that has caused many people to either blame the victim, or just turn their heads and consider domestic violence a "family" problem, thus ignoring the legal ramifications altogether. This area must be understood in order to determine how the distortion of the ideas that are being expressed, through the use of television and magazines, are directly related to the societal values being represented.      Ã‚  Ã‚   The first issue that I would like to analyze is how we as a society encourage violence against women.   Images flow into our homes everyday th... ...ved from our own lives.   Only then can we decided whether these portrayals are in fact the truth, or just more rhetoric being feed to us from the patriarchal view point of modern media outlets.       Works Cited       Berns, Nancy.   "My Problem and -How I Solved it: Domestic Violence in Women's Magazines". Sociology   Ã‚  Ã‚  Ã‚  Ã‚   Quarterly. 40 (Winter 1999) : 85-109 Carmody, Dianne Cyr.   Entertaining Violence. New York 1998. "Mixed Messages: Images of Domestic Violence   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   on "Reality " Television.  Ã‚   Ed. Mark Fishman and Gray Cavander.   Aldine De Gruyter Lemmey, Dorothy.   "Collective Silence for Collective Violence".   <1999 http//www.Feminista.com/   Ã‚  Ã‚  Ã‚  Ã‚  Ã‚  Ã‚   v1n12/lemmey.html : 1-6> Roland, John.   "Additional Amendments to the Constitution". <http://www.constitution.org/cons/afterten.htm>         

Thursday, October 24, 2019

Aggressive Parents, Aggressive Children Essay

Growing up, kids have a lot of influences in their life; from television to peers children will always absorb something. With this being said the biggest influence on a child would have to be the people there with the most- their family. Because this is unarguably true, it would then be fair to then assume that parental/ sibling aggression could have a big impact on future relationships caused by development. What is aggression one may ask? Aggression is a hostile, injurious, destructive behaviour or outlook especially when caused by frustration. Human development would be everything that happened from the moment a child thinks for the first time, then. Sigmund Freud was one psychologist who theorizes that those who have experienced trauma from aggression in the home will often use defense mechanisms to disregard unwanted emotions. This leaves a negative effect on the unconscious mind and makes a person act irrationally. By comparing cultures and examining how nature vs. urture, the theme of pies and how the ecological theory all come into play when dealing with the way children treat relationships, it is hoped that one will see that aggression in the home will indeed lead to negative relationships for the child’s near future. One key question many would ask and not for only this topic (but many on the mind in general), would be are these actions and thoughts merely influenced by parents, or are they born with th e â€Å"defect† and therefore forced to live with it. The argument of nature vs. nurture is a question that has baffled even the most renowned of psychologists. Both sides have strong supporting arguments therefore coming up with an end answer would be impossible for one to do. In Daena’s article, entitled â€Å"Is Aggressive Behaviour Biologically or Environmentally Based? † Daena proposes that aggression is learned. Supporting herself by linking aggression with Skinner’s rat, continuing by saying aggression is caused by positive reinforcement (reward). By calming a kid down with a toy, the child would have received the â€Å"reward†, now the child understands if he does this, then another â€Å"reward† should come. One way this could be seen in a household could be when a father cusses after he hurts himself. The child could subconsciously perceive that the pain and expression on the father going away shortly after was his reward, therefore the child takes on the habit. This does put some weight on the nurture side because the reward is what causes any outcome. But, Professor Richard Tremblay of the University of Montreal says that â€Å"We do not need to learn to aggress, but to not aggress. In this indirect argument with the other article mentioned Tremblay suggests that children are aggressive by nature and learn how to control their aggression at around 4 years old. When linking nature or nurture to aggression one must understand that they really can’t choose an option and be satisfied with their decision. â€Å"PIES† stands for the four kinds of development; physical, intellectual, emotional, social. When children witness aggression at home almost every kind of development a re interrupted. Physical development includes growth of bone muscles, motor skills and senses. Intellectual development includes the maturation of mental process, such as learning, imagination, memory and perception. When a child is used to seeing aggression exhibited by their parents, they will associate that violence will many things they see on a daily basis. For example the first time the child sees adults mating on television, etc. Their first instinct would usually be to believe that the couple is actually fighting. This shows that what they sense would be different from what’s actually happening therefore proving a negative outcome. Emotional development includes the maturation and evolution of emotions, social skills, identity, and morals. If a child grows up witnessing spousal abuse from an early age, and isn’t explained that it’s bad, then would that child not believe that this action is perfectly fine? Seeing the father only do this when he’s angry, the child could perceive that beating somebody is an output of anger for them as well. Social development includes the evolution of knowledge of how people interact, play, share, take turns, or talk socially. From an early stage if the child sees fighting, it is then safe to assume that their ‘evolution of knowledge based on how people interact’ will be evolving off of the witnessed negative action seen in the first place (spousal abuse, swearing parents, etc. ). A child’s development could be positive or negative based solely on the overall environment the child is living in. One may be lead to believe that aggression is taught by others, and then mirrored by the children whom the aggression will eventually attach itself too. Urie Bronfenbrenner’s Ecological Theory argues that ‘development’ is influenced by five environmental systems. The theory identifies five environmental systems. The five environmental systems are: Microsystem, Mesosystem, Exosystem, Macrosystem, and Chronosystem. The microsystem is the child’s immediate surroundings i. e. family, neighborhood and friends. This theory suggests that if the child lives in a damaged microsystem, the child’s development could also be damaged. The mesosystem is the connection seen between immediate environments i. e. parents to peers. This directly relates to the topic showing that if a child witness’s abuse, there’s a good chance they will mirror it with their peers. Children need people in order to become human†¦. It is primarily through observing, playing, and working with others both older and younger than he that a child discovers both what he can do and who he can become. †-Urie Bronfenbrenner (quotes. dictionary. com). This quote can be fitted to the topic of aggression in children because she basically explains that wi thout other humans, we would have no route for our personality/identity to take. The Macrosystem describes the culture of the child, anywhere from physical geographic, to wealth in the child’s area. Urie suggests that those that are living in lower class are more likely to commit crime. It must also be understood that children influenced by their environment is not conclusive. As children in some African regions see violence every day but learned to adapt with it as opposed to keeping it bottled up in their head. The final system is the Chronosystem. This monitors patterns of environmental events over time. Non-normative events may have a negative psychological effect, e. g. a recent divorce or death in the family. The change is too drastic for the child to cope with. With witnessed aggression, as it starts to become the normal in the child’s life, the child may seek to emulate it later on when the ‘normal’ aggression is missing. Urie Bronfenbenners theory does weigh in favor of the child learning the aggression because it all seems to tie into the child feeling a sense of normal. Based on the theory, children will emulate what they see, because if they didn’t emulate anything, they would have no guidance in their life. Their identity would be 100% their own. Therefore if aggression is their guide, aggression will be what children emulate.

Wednesday, October 23, 2019

Advantages and Disadvantages of the Behaviourist Approach Essay

Outline Two Advantages and Two Disadvantages of the Behaviourist Approach (12) One of the strengths of the behaviourist approach is that it only focuses on behaviour and behaviours that can be observed and manipulated. Consequently this approach has proved itself to be useful in experiments where behaviour can be observed and manipulated for desired effects such as the experiment Burrhus Frederic Skinner conducted on rats, manipulating them to press buttons and levers until they are given food and the experiment Ivan Petrovich Pavlov conducted on dogs where he manipulated them to salivate to the ringing of a bell, rather than to food. The behaviourist approach also concentrates on ‘here and now’ and what can be seen, rather than exploring a person’s past like the psychodynamic approach does. This is an advantage because it is not concerned with what cannot be seen and what happened in the past and many people do not know and believe that their past causes behaviour and personalities in their later life, and many people the think removing the undesirable behaviour is more important than understanding the causes of the behaviour. On the other hand, a disadvantage of the behaviourist approach is that the theories are too deterministic as behaviourists believe that our behaviour is determined only by environmental effects such as classical conditioning and operant conditioning which is a disadvantage as behaviour can be indeterministic and there can be no causes for it. It also undermines the amount of free will a person has and doesn’t consider that ever human can make choices about their behaviours and have moral responsibility for their behaviour which is a deficiency in the approach as a person can choose to change their behaviour and personality at any given moment and the environment doesn’t have to effect their decision. Also, the behaviourist approach emphasises too much on nurture. It focuses only on the environment effects on a person, so it completely ignores effects nature can have on a purpose and disregards genetics as an explanation of behaviour which is a disadvantage as behaviour can be altered and modified by nature every day in different ways like where a person  lives, where they visit, even what bus route they take etc. Furthermore, a question often put to behaviourists is ‘If learning is the only factor that makes us who we are, then we should all be capable of becoming whatever we want to be’ and many behaviourists cannot justify this question properly, the bottom line is that there are many different factors affecting our abilities other than learning. In addition, the theories of behaviourism have been mainly tested on animals so the findings may not completely apply to human behaviour, which is much more a lot more complex.